Neodymium fluoride

Base Information

  • PRODUCT:Neodymium fluoride
  • CAS.:13709-42-7
  • MF:NdF3
  • Molecular Weight:201.235
  • Purity:99%
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Product Details

CAS： 13709-42-7

MF： NdF3

Appearance： Light grey powder

Top Purity Quality Manufacturer Supply Neodymium fluoride 13709-42-7 with Efficient Transportation

  • Molecular Formula:NdF3
  • Molecular Weight:201.235
  • Appearance/Colour:Light grey powder 
  • Melting Point:1410 °C 
  • Boiling Point:19.5 °C at 760 mmHg 
  • PSA：0.00000 
  • Density:6.65 
  • LogP:1.26060 

Neodymium trifluoride(Cas 13709-42-7) Usage

Hazard

Irritant.

Flammability and Explosibility

Nonflammable

InChI:InChI=1/FH.Nd/h1H;/q;+3/p-1

13709-42-7 Relevant articles

Phase analyses of lanthanide oxide fluorides

Shinn, Dennis B.,Eick, Harry A.

, p. 232 - 235 (1969)

Approximate composition limits and latti...

Synthesis and characterization of Ba1-xNdxF2+x (0.00 ≤ x ≤ 1.00)

Grover,Achary,Patwe,Tyagi

, p. 1101 - 1111 (2003)

A series of mixed fluorides with general...

Laser development of rare-earth doped crystals

Vieira Jr.,Ranieri,Tarelho,Wetter,Baldochi,Gomes,De Matos,De Rossi,Nogueira,Courrol,Barbosa,Maldonado,Morato

, p. 231 - 239 (2002)

Rare earth doped laser crystals present ...

Heterometallic Ln/Hg compounds with fluorinated thiolate ligands

Banerjee, Santanu,Emge, Thomas J.,Brennan, John G.

, p. 6307 - 6312 (2004)

The early lanthanide benzenefluorothiola...

Solubility of YF3, CeF3, PrF3, NdF 3, and DyF3 in solutions containing sulfuric and phosphoric acids

Lokshin,Tareeva

, p. 1830 - 1834 (2007)

The solubility of YF3, CeF3, PrF3, NdF3,...

Spectroscopic characterization of Ho3+ ion-doped fluoride glass

Florez,Oliveira,Flórez,Gómez,Nunes

, p. 238 - 242 (2006)

Among the new optical materials availabl...

Optical properties of Nd3+-doped fluorophosphate glasses

Binnemans,Van Deun,Gorller-Walrand,Adam

, p. 455 - 460 (1998)

Optical absorption spectra of Nd3+-doped...

Synthesis and characterization of LnF(HF)(BF4)2 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, and Dy), and crystal structures of LnF(HF)(BF4)2 (Ln = Pr, Nd) and La(BF4) 3

Mazej, Zoran,Goreshnik, Evgeny,Hironaka, Kohei,Katayama, Yasushi,Hagiwara, Rika

, p. 2309 - 2315 (2009)

Rare earth trifluorides (Ln = La, Ce, Pr...

Hydrofluoride synthesis of fluorides of some rare-earth elements

Kalinnikov,Makarov,Tikhomirova,Elizarova,Kuznetsov

, p. 1760 - 1764 (2002)

Thermal gravimetric, X-ray phase, IR spe...

High-quality sodium rare-earth fluoride nanocrystals: Controlled synthesis and optical properties

Mai, Hao-Xin,Zhang, Ya-Wen,Si, Rui,Yan, Zheng-Guang,Sun, Ling-Dong,You, Li-Ping,Yan, Chun-Hua

, p. 6426 - 6436 (2006)

We report a general synthesis of high-qu...

Phase relation studies in Pb1-xM′xF 2+x systems (0.0≤x≤1.0; M′=Nd3+, Eu 3+ and Er3+)

Tyagi,Patwe,Achary,Mallia

, p. 1746 - 1757 (2004)

In this communication we report the synt...

Lanthanide pentafluorophenolates. Synthesis, structure and luminescent properties

Maleev, Alexander A.,Fagin, Anatoly A.,Ilichev, Vasily A.,Lopatin, Mikhail A.,Konev, Alexey N.,Samsonov, Maksim A.,Fukin, Georgy K.,Bochkarev, Mikhail N.

, p. 126 - 132 (2013/11/19)

The pentafluorophenolates of lanthanides...

X-ray magnetic circular dichroism (XMCD) study of a methoxide-bridged DyIII-CrIII cluster obtained by fluoride abstraction from cis-[CrIIIF2(phen)2]+

Dreiser, Jan,Pedersen, Kasper S.,Birk, Torben,Schau-Magnussen, Magnus,Piamonteze, Cinthia,Rusponi, Stefano,Weyhermueller, Thomas,Brune, Harald,Nolting, Frithjof,Bendix, Jesper

, p. 7842 - 7847 (2012/09/22)

An isostructural series of dinuclear chr...

Infrared spectra and quantum chemical calculations of the bridge-bonded HC(F)LnF2 (Ln = La-Lu) complexes

Gong, Yu,Wang, Xuefeng,Andrews, Lester,Chen, Mingyang,Dixon, David A.

, p. 4443 - 4452 (2011/10/10)

Lanthanide metal atoms, produced by lase...

The versatility of solid-state metathesis reactions: From rare earth fluorides to carboiimides

Unverfehrt, Leonid,Glaser, Jochen,Stroebele, Markus,Tragl, Sonja,Gibson, Katharina,Meyer, H.-Juergen

, p. 479 - 483 (2009/06/17)

The new carbodiimide compounds LaF(CN2) ...

13709-42-7 Process route

NdCl<sub>3</sub>*NdF<sub>3</sub>

NdCl3*NdF3

neodymium(III) fluoride
13709-42-7

neodymium(III) fluoride

neodymium trichloride
10024-93-8

neodymium trichloride

Conditions
Conditions Yield
In neat (no solvent, solid phase); decompn. at 595°C;
ammonium fluoride

ammonium fluoride

neodymium(III) oxide

neodymium(III) oxide

neodymium(III) fluoride
13709-42-7

neodymium(III) fluoride

Conditions
Conditions Yield
In neat (no solvent); excess fluoride, 200°C, Pt-vessel; removal of excess fluoride on heating in a stream of dry inert gas to 450°C;;
In hydrogenchloride; dissolving oxide in aq. HCl, pptn. with excess aq. NH4F, filtration, drying, dehydration on heating ppt. with excess powdered NH4F to 360°C in a dry stream of He or Ne (O2-free) for 5h;;
In hydrogenchloride; dissolving oxide in aq. HCl, pptn. with excess aq. NH4F, filtration, drying, dehydration on heating ppt. with excess powdered NH4F to 360°C in a dry stream of He or Ne (O2-free) for 5h;;
With HF; In hydrogen fluoride; aq. HF; lanthanide trifluoride is treated with 40% hydrofluoric acid with stirring, decanting the HF, drying under an infrared heater at 50°C, mixing with NH4F, heating at 500°C; XRD, DTA;
With KOH or NaOH; In nitric acid; aq. HNO3; High Pressure; oxide dissolved in 10% HNO3, mixed with NH4F soln., 10% KOH (or NaOH) added to adjust the system to pH 4-5, ppt. transfered to autoclave, sealed, maintained at 80-180°C for 12-24 h, cooled to room temp.; ppt. filtered, washed (H2O), dried in air at 80°C; nanoparticles,detn. by XRD;
In neat (no solvent, solid phase); according to Keller, C., Schumtz, H., J. Inorg. Nucl. Chem. 1965, 27, 900.; Nd2O3 mixed with 10-fold molar excess of NH4F at 100°C in a corundum beaker in air; NH4F excess removed by sublimation; heated to 380°C under vac.;

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